Response
Makarieva A.M., Gorshkov V.G. (2006): Response to anonymous critique
of biotic pump
regarding the role of water vapor in meteorology.
www.biotic-regulation.pl.ru/pump/comm5.htm
It is not claimed in our work that "up to now water vapor effect are not taken into
account (evaporation) in the change of the lowering or rising of
pressure (column weight)". In fact, we stress that the effect of the
non-equilibrium distribution of water vapor is WELL-KNOWN. It would
be indeed absurd to say that water vapor itself has been unknown in
atmospheric and meteorological science.
The formal apparatus involving potential temperature
referred to in the comment, has indeed been used to calculate the
amounts of water vapour in the atmosphere. What is stated in the work
is that the observed properties of the water vapor distribution have not been
appreciated in its importance, that is, no conclusions about the
existence of the evaporative force were made from this knowledge.
The comment says: "The central physical concept that lack of
hydrostatic equilibrium of water vapor do not hold because water
vapor molecules are mixed in the atmosphere and it is only meaningful
to talk about hydrostatic equilibrium (the vertical pressure gradient
force balanced by the gravity force) for the atmospheric composition
as a whole."
The hydrostatic equilibrium of the atmospheric composition including
various gases (as a whole) is impossible. It counteracts the basics
of gas physics. It is similar to saying that if you take two jars
with different gases but having equal pressure and make them contact
each other, nothing will happen because the pressures are equal. In
reality, however, the gases will mix up quickly, and in the resulting
stationary state not only pressures, but also the concentrations of
gases in the two jars will be the same.
The same is true for the gravitational field, where the stationary
stable state is the state when each gas is distributed along the
vertical with its own scale height determined by its molecular mass.
The excessive pressure of one gas cannot compensate the insufficient
pressure of another. As we mentioned in the pre-print, this physical
principle is responsible for the phenomenon of osmosis: when you
bring in contact two solutions (or gaseous mixtures) of the same
total pressure but with different concentrations of the compounds,
the concentrations start to equate. But, if there is a membrane which
prevent compound X to move from one solution to another, while
the second compound Y can move freely, the resulting stationary case
will be when compound Y (e.g. water), trying to equate its
concentrations on both sides of the membrane, will accumulate on one
side of this membrane in excess, producing the uncompensated
pressure. The force associated with this effect is huge, tearing in
pieces metallic ships and allowing seeds to effectively suck in the ambient
water.
At the same time, if there were no membrane, the concentrations of
both solutions would equate producing no pressure gradient.
In the atmosphere, the role of membrane which differently treats the
different (condensable and non-condensable) air constituents is
played by the vertical temperature gradient. Through condensation
governed by the temperature-dependent Clausius-Clapeyron law, it
does not allow water molecules to move upward in quantities
sufficient for establishment of the hydrostatic equilibrium. At the
same time it does not impede vertical propagation of the
non-condensable air constituents. So, in the stationary case, the
evaporative force persists and is large enough to generate the
atmospheric circulation.
As far as the water vapour mixing ratio is very small, one can say
that atmosphere as a whole is in hydrostatic equilibrium (to the
accuracy of this few per cent). However, it appears that namely these
few per cent determine the major processes in the atmosphere.
We do claim that this effect has not been known in the meteorological
and atmospheric science. Even the simple fact that the scale height
of atmospheric water vapor (2 km) as compared to the much larger scale
height of other air gases (8 km) can be easily calculated from the
Clausius-Clapeyron equation using the observed vertical temperature
lapse rate, is missing from the meteorological textbooks, where it is
presented merely like an empirical generalization. Only in 1995
Weaver and Ramanathan noted (parenthetically) that these 2 km could
indeed be retrieved in this way. And no one has ever mentioned the
vertical force associated with the non-equilibrium vertical water pressure
gradient.
Since these effects are as real as is the gravitational field and the
observed temperature lapse rate on Earth, there is in our view no reason
to describe them for some idealized planet.
|